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Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and selenium, as well.
Main group organometallic chemistry concerns the preparation and properties of main-group elements directly bonded to carbon. The inventory is large. The inventory is large. The compounds exhibit a wide range of properties, including ones that are water-stable and others that are pyrophoric . [ 1 ]
The 18-electron rule is a chemical rule of thumb used primarily for predicting and rationalizing formulas for stable transition metal complexes, especially organometallic compounds. [1] The rule is based on the fact that the valence orbitals in the electron configuration of transition metals consist of five ( n −1)d orbitals, one n s orbital ...
Organonickel chemistry is a branch of organometallic chemistry that deals with organic compounds featuring nickel-carbon bonds. [1] [2] They are used as a catalyst, as a building block in organic chemistry and in chemical vapor deposition. Organonickel compounds are also short-lived intermediates in organic reactions.
Organozirconium chemistry is the science of exploring the properties, structure, and reactivity of organozirconium compounds, which are organometallic compounds containing chemical bonds between carbon and zirconium. [2] Organozirconium compounds have been widely studied, in part because they are useful catalysts in Ziegler-Natta polymerization.
Most metal alkyl complexes contain other, non-alkyl ligands. Great interest, mainly theoretical, has focused on the homoleptic complexes. Indeed, the first reported example of a complex containing a metal-sp 3 carbon bond was the homoleptic complex diethylzinc.
Organoiridium chemistry is the chemistry of organometallic compounds containing an iridium-carbon chemical bond. [2] Organoiridium compounds are relevant to many important processes including olefin hydrogenation and the industrial synthesis of acetic acid. They are also of great academic interest because of the diversity of the reactions and ...
Chemistry portal; Organometallic chemistry is the study of chemical compounds containing bonds between carbon and a metal. The term "metal" is defined deliberately broadly in this context and may include elements, such as silicon or boron, which are not metallic but are considered to be metalloids.