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  2. Cyclic compound - Wikipedia

    en.wikipedia.org/wiki/Cyclic_compound

    Cyclic compounds may or may not exhibit aromaticity; benzene is an example of an aromatic cyclic compound, while cyclohexane is non-aromatic. In organic chemistry, the term aromaticity is used to describe a cyclic (ring-shaped), planar (flat) molecule that exhibits unusual stability as compared to other geometric or connective arrangements of ...

  3. Bicyclic molecule - Wikipedia

    en.wikipedia.org/wiki/Bicyclic_molecule

    Numbering of the carbon chain always begins at one bridgehead atom (where the rings meet) and follows the carbon chain along the longest path, to the next bridgehead atom. Then numbering is continued along the second longest path and so on. Fused and bridged bicyclic compounds get the prefix bicyclo, whereas spirocyclic compounds get the prefix ...

  4. Ring-opening polymerization - Wikipedia

    en.wikipedia.org/wiki/Ring-opening_polymerization

    In polymer chemistry, ring-opening polymerization (ROP) is a form of chain-growth polymerization in which the terminus of a polymer chain attacks cyclic monomers to form a longer polymer (see figure). The reactive center can be radical, anionic or cationic. Ring-opening of cyclic monomers is often driven by the relief of bond-angle strain.

  5. Heterocyclic compound - Wikipedia

    en.wikipedia.org/wiki/Heterocyclic_compound

    Heterocyclic organic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of organic heterocycles. [2] Examples of heterocyclic compounds include all of the nucleic acids, the majority of drugs, most biomass (cellulose and related materials), and many natural and synthetic dyes. More than half of ...

  6. Cycloalkane - Wikipedia

    en.wikipedia.org/wiki/Cycloalkane

    In organic chemistry, the cycloalkanes (also called naphthenes, but distinct from naphthalene) are the monocyclic saturated hydrocarbons. [1] In other words, a cycloalkane consists only of hydrogen and carbon atoms arranged in a structure containing a single ring (possibly with side chains), and all of the carbon-carbon bonds are single.

  7. Catenation - Wikipedia

    en.wikipedia.org/wiki/Catenation

    In chemistry, catenation is the bonding of atoms of the same element into a series, called a chain. [1] A chain or a ring may be open if its ends are not bonded to each other (an open-chain compound), or closed if they are bonded in a ring (a cyclic compound). The words to catenate and catenation reflect the Latin root catena, "chain".

  8. Organic chemistry - Wikipedia

    en.wikipedia.org/wiki/Organic_chemistry

    Biomolecular chemistry is a major category within organic chemistry which is frequently studied by biochemists. Many complex multi-functional group molecules are important in living organisms. Some are long-chain biopolymers, and these include peptides, DNA, RNA and the polysaccharides such as starches in animals and celluloses in plants.

  9. Ring expansion and contraction - Wikipedia

    en.wikipedia.org/wiki/Ring_expansion_and_contraction

    Examples include high impact applications of the Beckmann rearrangement (for introduction of nitrogen into codeine) [14] and the Baeyer-Villiger oxidation (introduction of oxygen to cage-annulated ethers) [15] in synthesis. Both occur with the expulsion of a leaving group as the alkyl group migrates onto the exocyclic heteroatom, which is ...