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The Stark effect is the shifting and splitting of spectral lines of atoms and molecules due to the presence of an external electric field. It is the electric-field analogue of the Zeeman effect , where a spectral line is split into several components due to the presence of the magnetic field .
Traité élémentaire de chimie [1] is a textbook written by Antoine Lavoisier published in 1789 and translated into English by Robert Kerr in 1790 under the title Elements of Chemistry in a New Systematic Order containing All the Modern Discoveries. [2] It is considered to be the first modern chemical textbook. [3]
In chemistry, Le Chatelier's principle (pronounced UK: / l ə ʃ æ ˈ t ɛ l j eɪ / or US: / ˈ ʃ ɑː t əl j eɪ /) [1] is a principle used to predict the effect of a change in conditions on chemical equilibrium. [2] Other names include Chatelier's principle, Braun–Le Chatelier principle, Le Chatelier–Braun principle or the equilibrium ...
For example, in copper 29 Cu, according to the Madelung rule, the 4s subshell (n + l = 4 + 0 = 4) is occupied before the 3d subshell (n + l = 3 + 2 = 5). The rule then predicts the electron configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 9 4s 2, abbreviated [Ar] 3d 9 4s 2 where [Ar] denotes the configuration of argon, the preceding noble gas.
Stark spectroscopy (sometimes known as electroabsorption/emission spectroscopy) is a form of spectroscopy based on the Stark effect.In brief, this technique makes use of the Stark effect (or electrochromism) either to reveal information about the physiochemical or physical properties of a sample using a well-characterized electric field or to reveal information about an electric field using a ...
Joseph-Louis Proust was born on 26 September 1754 in Angers, France.His father served as an apothecary in Angers. Joseph studied chemistry in his father's shop and later went to Paris where he gained the appointment of apothecary in chief to the Salpêtrière. [2]
The law was first proposed in 1817 by Theodor Grotthuss and in 1842, independently, by John William Draper. [5] This is considered to be one of the two basic laws of photochemistry. The second law is the Stark–Einstein law, which says that primary chemical or physical reactions occur with each photon absorbed. [5]
A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by an atom or group. [1] [2] [3] It can be represented generically as: + +