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Substitutional solid solution strengthening occurs when the solute atom is large enough that it can replace solvent atoms in their lattice positions. Some alloying elements are only soluble in small amounts, whereas some solvent and solute pairs form a solution over the whole range of binary compositions.
For this strengthening mechanism, solute atoms of one element are added to another, resulting in either substitutional or interstitial point defects in the crystal (see Figure on the right). The solute atoms cause lattice distortions that impede dislocation motion, increasing the yield stress of the material. Solute atoms have stress fields ...
For substitutional solid solutions, the Hume-Rothery rules are as follows: The atomic radius of the solute and solvent atoms must differ by no more than 15%: [1] % = % %. The crystal structures of solute and solvent must be similar.
In metal alloys with substitutional solute elements, such as aluminum-magnesium alloys, dynamic strain aging leads to negative strain rate sensitivity which causes instability in plastic flow. [4] The diffusion of solute elements around a dislocation can be modeled based on the energy required to move a solute atom across the slip plane of the ...
The IUPAC definition of a solid solution is a "solid in which components are compatible and form a unique phase". [3]The definition "crystal containing a second constituent which fits into and is distributed in the lattice of the host crystal" given in refs., [4] [5] is not general and, thus, is not recommended.
The strength of the metal was found to vary reciprocally with the size of the subgrain, which is analogous to the Hall–Petch equation. The subgrain boundary strengthening also has a breakdown point of around a subgrain size of 0.1 μm, which is the size where any subgrains smaller than that size would decrease yield strength. [5]
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[24] [25] Many researchers suggested that the CSF compartment constitutes a sink for interstitial solute and fluid clearance from the brain parenchyma. [ citation needed ] However, the distances between the interstitial fluid and the CSF in the ventricles and subarachnoid space are too great for the efficient removal of interstitial ...