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The solubility increases down the column as the alkali metal ions become larger and the lattice enthalpies decrease. [1] All alkali metal hydroxides are strong bases, meaning that they dissociate completely in solution to give OH − ions. As strong bases, alkali hydroxides are highly corrosive and are used in cleaning products.
The alkali metal hydroxides are the most basic known hydroxides. [10]: 87 Recent research has suggested that the explosive behavior of alkali metals in water is driven by a Coulomb explosion rather than solely by rapid generation of hydrogen itself. [105] All alkali metals melt as a part of the reaction with water.
In chemistry, metal hydroxides are a family of compounds of the form M n+ (OH) n, where M is a metal. They consist of hydroxide (OH −) anions and metallic cations, [1] and are often strong bases. Some metal hydroxides, such as alkali metal hydroxides, ionize completely when dissolved. Certain metal hydroxides are weak electrolytes and ...
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise. The substances are listed in alphabetical order.
The hydroxide ion appears to rotate freely in crystals of the heavier alkali metal hydroxides at higher temperatures so as to present itself as a spherical ion, with an effective ionic radius of about 153 pm. [38] Thus, the high-temperature forms of KOH and NaOH have the sodium chloride structure, [39] which gradually freezes in a ...
A basic salt of an alkali metal or alkaline earth metal [2] (this includes Mg(OH) 2 (magnesium hydroxide) but excludes NH 3 ). Any base that is soluble in water and forms hydroxide ions [3] [4] or the solution of a base in water. [5] (This includes both Mg(OH) 2 and NH 3, which forms NH 4 OH.) The second subset of bases is also called an ...
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.