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The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
Polyatomic cations of the same element are named as the element name preceded by di-, tri-, etc., e.g.: Hg 2+ 2 dimercury(2+) Polyatomic cations made up of different elements are named either substitutively or additively, e.g.: PH + 4 phosphanium; SbF + 4 tetrafluorostibanium (substitutive) or tetrafluoridoantimony(1+)
The main purpose of chemical nomenclature is to disambiguate the spoken or written names of chemical compounds: each name should refer to one compound. Secondarily, each compound should have only one name, although in some cases some alternative names are accepted. Preferably, the name should also represent the structure or chemistry of a compound.
Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule. For example, the conjugate base of sulfuric acid (H 2 SO 4) is the polyatomic hydrogen sulfate anion (HSO − 4).
IUPAC nomenclature is used for the naming of chemical compounds, based on their chemical composition and their structure. [1] For example, one can deduce that 1-chloropropane has a Chlorine atom on the first carbon in the 3-carbon propane chain.
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
2 ion, found in mercury(I) (mercurous) compounds. The existence of the metal–metal bond in Hg(I) compounds was established using X-ray studies in 1927 [2] [page needed] and Raman spectroscopy in 1934 [3] making it one of the earliest, if not the first, metal–metal covalent bonds to be characterised. Other mercury polycations are the linear ...
The circumstances under which a compound will have ionic or covalent character can typically be understood using Fajans' rules, which use only charges and the sizes of each ion. According to these rules, compounds with the most ionic character will have large positive ions with a low charge, bonded to a small negative ion with a high charge. [25]