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In analytical chemistry, the detection limit, lower limit of detection, also termed LOD for limit of detection or analytical sensitivity (not to be confused with statistical sensitivity), is the lowest quantity of a substance that can be distinguished from the absence of that substance (a blank value) with a stated confidence level (generally 99%).
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
A free concentration [A] ... the detection limit for that species will be lower. ... The minimization can be performed in a spreadsheet application such as EXCEL by ...
Downloadable EXCEL program for the determination of the Most Probable Numbers (MPN), their standard deviations, confidence bounds and rarity values according to Jarvis, B., Wilrich, C., and P.-T. Wilrich: Reconsideration of the derivation of Most Probable Numbers, their standard deviations, confidence bounds and rarity values.
Using a spectrophotometer, it is possible to quantitatively determine the nitrite concentration. The detection limit of the Griess test generally ranges between 0.02 and 2 μM, depending on the exact details of the specific components used in the Griess reagent.
Because of the complex inter-relationship between analytical method, sample concentration, limits of detection and method precision, the management of Analytical Quality Control is undertaken using a statistical approach to determine whether the results obtained lie within an acceptable statistical envelope.
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Stripping analysis has the following properties: sensitive and reproducible (RSD<5%) method for trace metal ion analysis in aqueous media, 2) concentration limits of detection for many metals are in the low ppb to high ppt range (S/N=3) and this compares favorably with AAS or ICP analysis, field deployable instrumentation that is inexpensive ...