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1,2-Dichloroethylene or 1,2-DCE is the name for a pair of organochlorine compounds with the molecular formula C 2 H 2 Cl 2. The two compounds are isomers, each being colorless liquids with a sweet odor. It can exist as either of two geometric isomers, cis-1,2-dichloroethene or trans-1,2-dichloroethene, but is often used as a mixture of the two ...
The two cis stereoisomers of 1,2-substituted cyclohexanes behave like meso compounds at room temperature in most cases. At room temperature, most 1,2-disubstituted cyclohexanes undergo rapid ring flipping (exceptions being rings with bulky substituents), and as a result, the two cis stereoisomers behave chemically identically with chiral ...
Cyclopentane is a minor component of automobile fuel, with its share in US gasoline varying between 0.2 and 1.6% in early 1990s [8] and 0.1 to 1.7% in 2011. [9] Its research and motor octane numbers are reported as 101 or 103 and 85 or 86 respectively. [10] [11]
1,3-Dichloropropene, sold under diverse trade names, is an organochlorine compound with the formula C 3 H 4 Cl 2. It is a colorless liquid with a sweet smell. It is a colorless liquid with a sweet smell.
For 1,3-disubstituted cyclohexanes, the cis form is diequatorial and the flipped conformation suffers additional steric interaction between the two axial groups. trans-1,3-Disubstituted cyclohexanes are like cis-1,2- and cis-1,4- and can flip between the two equivalent axial/equatorial forms. [2]
Because (1R,3R)-1,2,3-trimethylcyclopentane is a cycloalkane, its three methyl substituents are capable of exhibiting cis/trans isomerism. This implies that the methyl groups in positions 1,2, and 3 may occupy different spatial arrangements (i.e.they may either lay cis or trans with respect to each other).
However, conformationally constrained systems like cis-1,2-divinyl cyclopropanes can undergo the rearrangement in the boat conformation. It is currently generally accepted that most Cope rearrangements follow an allowed concerted route through a Hückel aromatic transition state and that a diradical intermediate is not formed.
1,2-Dimethylcyclopropane is a cycloalkane consisting of a cyclopropane ring substituted with two methyl groups attached to adjacent carbon atoms. [1] It has three stereoisomers , one cis -isomer and a pair of trans - enantiomers , which differ depending on the orientation of the two methyl groups.