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Buffer capacity rises to a local maximum at pH = pK a. The height of this peak depends on the value of pK a. Buffer capacity is negligible when the concentration [HA] of buffering agent is very small and increases with increasing concentration of the buffering agent. [3] Some authors show only this region in graphs of buffer capacity. [2]
The Henderson–Hasselbalch equation can be used to estimate the pH of a buffer solution by approximating the actual concentration ratio as the ratio of the analytical concentrations of the acid and of a salt, MA. The equation can also be applied to bases by specifying the protonated form of the base as the acid.
As long as all the pure minerals (or compounds) are present in a buffer assemblage, the oxidizing conditions are fixed on the curve for that buffer. Pressure has only a minor influence on these buffer curves for conditions in the Earth's crust. MH: magnetite-hematite: 4 Fe 3 O 4 + O 2 ⇌ 6 Fe 2 O 3. NiNiO: nickel-nickel oxide: 2 Ni + O 2 ⇌ 2 NiO
Defining equation (physical chemistry) List of electromagnetism equations; List of equations in classical mechanics; List of equations in quantum mechanics; List of equations in wave theory; List of photonics equations; List of relativistic equations; Relativistic wave equations
Any condition that changes the balance of one of the buffer systems, also changes the balance of all the others because the buffer systems actually buffer one another by shifting hydrogen ions back and forth from one to the other. The isohydric principle has special relevance to in vivo biochemistry where multiple acid/ base pairs are in ...
In physics, there are equations in every field to relate physical quantities to each other and perform calculations. Entire handbooks of equations can only summarize most of the full subject, else are highly specialized within a certain field. Physics is derived of formulae only.
Where it would get really interesting would be if Clemson upsets SMU in the ACC title game or UNLV upsets Boise State in the Mountain West title game and causes a bid to be “stolen” — i.e ...
In fluid dynamics, the Buckley–Leverett equation is a conservation equation used to model two-phase flow in porous media. [1] The Buckley–Leverett equation or the Buckley–Leverett displacement describes an immiscible displacement process, such as the displacement of oil by water, in a one-dimensional or quasi-one-dimensional reservoir.