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In inorganic chemistry, Fajans' rules, formulated by Kazimierz Fajans in 1923, [1] [2] [3] are used to predict whether a chemical bond will be covalent or ionic, and depend on the charge on the cation and the relative sizes of the cation and anion. They can be summarized in the following table:
Yet, clearly the bond angles between all these molecules deviate from their ideal geometries in different ways. Bent's rule can help elucidate these apparent discrepancies. [5] [20] [21] Electronegative substituents will have more p character. [5] [20] Bond angle has a proportional relationship with s character and an inverse relationship with ...
Carbon–oxygen bond; Carbon–hydrogen bond; Catch bond; Cation–π interaction; Cation–cation bond; Chalcogen bond; Charge-shift bond; Chemical bonding model; Chemical bonding of water; Chemical specificity; Compliance constants; Cooperative binding; Cooperativity; Coordinate covalent bond; Coordination geometry; Ligand isomerism ...
An online system named ePathshala, a joint initiative of NCERT and Ministry of Education, has been developed for broadcasting educational e-schooling resources including textbooks, audio, video, publications, and a variety of other print and non-print elements, [18] ensuring their free access through mobile phones and tablets (as EPUB) and from ...
A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds or through the sharing of electrons as in covalent bonds, or some combination of these effects.
Bond order is the number of chemical bonds between a pair of atoms. The bond order of a molecule can be calculated by subtracting the number of electrons in anti-bonding orbitals from the number of bonding orbitals, and the resulting number is then divided by two. A molecule is expected to be stable if it has bond order larger than zero.
The inert-pair effect is the tendency of the two electrons in the outermost atomic s-orbital to remain unshared in compounds of post-transition metals.The term inert-pair effect is often used in relation to the increasing stability of oxidation states that are two less than the group valency for the heavier elements of groups 13, 14, 15 and 16.
The hydroxyl group (OH) bonds to the carbon that has the greater number of carbon-carbon bonds, while the hydrogen bonds to the carbon on the other end of the double bond, that has more carbon–hydrogen bonds. The chemical basis for Markovnikov's Rule is the formation of the most stable carbocation during the addition process. Adding the ...
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