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  2. Calibration curve - Wikipedia

    en.wikipedia.org/wiki/Calibration_curve

    A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]

  3. Standard addition - Wikipedia

    en.wikipedia.org/wiki/Standard_addition

    The silver concentration in the test sample is the x-intercept of the plot. The dilution factor is multiplied by this initial concentration to determine the original concentration. Matrix effects occur even with methods such as plasma spectrometry , which have a reputation for being relatively free from interferences.

  4. Mayo–Lewis equation - Wikipedia

    en.wikipedia.org/wiki/Mayo–Lewis_equation

    From the definition of reactivity ratios, several special cases can be derived: >> If both reactivity ratios are very high, the two monomers only react with themselves and not with each other. This leads to a mixture of two homopolymers. >. If both ratios are larger than 1, homopolymerization of each monomer is favored.

  5. Errors and residuals - Wikipedia

    en.wikipedia.org/wiki/Errors_and_residuals

    Since this is a biased estimate of the variance of the unobserved errors, the bias is removed by dividing the sum of the squared residuals by df = n − p − 1, instead of n, where df is the number of degrees of freedom (n minus the number of parameters (excluding the intercept) p being estimated - 1). This forms an unbiased estimate of the ...

  6. Biasing - Wikipedia

    en.wikipedia.org/wiki/Biasing

    A graphical representation of the current and voltage properties of a transistor; the bias is selected so that the operating point permits maximum signal amplitude without distortion. In electronics , biasing is the setting of DC ( direct current ) operating conditions (current and voltage) of an electronic component that processes time-varying ...

  7. Gran plot - Wikipedia

    en.wikipedia.org/wiki/Gran_plot

    The Gran plot is based on the Nernst equation which can be written as = + ⁡ {+} where E is a measured electrode potential, E 0 is a standard electrode potential, s is the slope, ideally equal to RT/nF, and {H +} is the activity of the hydrogen ion.

  8. Matrix (chemical analysis) - Wikipedia

    en.wikipedia.org/wiki/Matrix_(chemical_analysis)

    In chemical analysis, matrix refers to the components of a sample other than the analyte [1] of interest. The matrix can have a considerable effect on the way the analysis is conducted and the quality of the results are obtained; such effects are called matrix effects. [2]

  9. Multicollinearity - Wikipedia

    en.wikipedia.org/wiki/Multicollinearity

    However, because income is equal to expenses plus savings by definition, it is incorrect to include all 3 variables in a regression simultaneously. Similarly, including a dummy variable for every category (e.g., summer, autumn, winter, and spring) as well as an intercept term will result in perfect collinearity. This is known as the dummy ...