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In two papers outlining his "theory of atomicity of the elements" (1857–58), Friedrich August Kekulé was the first to offer a theory of how every atom in an organic molecule was bonded to every other atom. He proposed that carbon atoms were tetravalent, and could bond to themselves to form the carbon skeletons of organic molecules.
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In quantum chemistry, the quantum theory of atoms in molecules (QTAIM), sometimes referred to as atoms in molecules (AIM), is a model of molecular and condensed matter electronic systems (such as crystals) in which the principal objects of molecular structure - atoms and bonds - are natural expressions of a system's observable electron density distribution function.
Molecular models may be created for several reasons – as pedagogic tools for students or those unfamiliar with atomistic structures; as objects to generate or test theories (e.g., the structure of DNA); as analogue computers (e.g., for measuring distances and angles in flexible systems); or as aesthetically pleasing objects on the boundary of ...
The Mystery of Matter. MacMillan. ISBN 0-333-76002-6. Bernard Pullman (1998). The Atom in the History of Human Thought. Translated by Axel Reisinger. Oxford University Press. ISBN 0-19-511447-7. Jean Perrin (1910) [1909]. Brownian Movement and Molecular Reality. Translated by F. Soddy. Taylor and Francis. Ida Freund (1904).
Corpuscularianism is similar to the theory of atomism, except that where atoms were supposed to be indivisible, corpuscles could in principle be divided.In this manner, for example, it was theorized that mercury could penetrate into metals and modify their inner structure, a step on the way towards the production of gold by transmutation.
The kinetic theory of gases deals not only with gases in thermodynamic equilibrium, but also very importantly with gases not in thermodynamic equilibrium. This means using Kinetic Theory to consider what are known as "transport properties", such as viscosity, thermal conductivity, mass diffusivity and thermal diffusion.
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