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Right: Polymer chains which have been cross linked to give a rigid 3D thermoset polymer In materials science , a thermosetting polymer , often called a thermoset , is a polymer that is obtained by irreversibly hardening (" curing ") a soft solid or viscous liquid prepolymer ( resin ). [ 1 ]
These differences arise from how the polymer chains are held together. Historically, thermoset polymer systems that were processable by virtue of topology changes within the covalent networks as mediated by bond exchange reactions were also developed by James Economy’s group at UIUC in the 1990s [ 4 ] [ 5 ] including consolidation of ...
A thermoset polymer matrix is a synthetic polymer reinforcement where polymers act as binder or matrix to secure in place incorporated particulates, fibres or other reinforcements. They were first developed for structural applications, [ 1 ] such as glass-reinforced plastic radar domes on aircraft and graphite - epoxy payload bay doors on the ...
This property is unusual for thermosetting plastics and allows easy recycling. This PHT has a Young's modulus exceeding 10 GPa, which is among the highest for a thermosetting plastic; it can be further increased by ~50% by dispersing carbon nanotubes in the polymer. The PHT is brittle, and cracks when strained to 1%.
Thermosetting plastics are polymer materials which are liquid or malleable at low temperatures, but which change irreversibly to become hard at high temperatures. Subcategories This category has only the following subcategory.
Thermoplastic vulcanizates were first reported in 1962 by A.M. Gessler and W.H. Haslett. [4] In 1973, W.K. Fisher reported the dynamic vulcanization process through his prior work on polypropylene and EPDM rubber-based TPVs with peroxides as a cross-linking agent.
Sulfur forms cross-linking bridges between sections of polymer chains which affects the mechanical and electronic properties. [citation needed] Many products are made with vulcanized rubber, including tires, shoe soles, hoses, and conveyor belts. The term vulcanization is derived from Vulcan, the Roman god of fire.
This thermoset material can be used as an alternative to polyester and epoxy materials as the thermoset polymer matrix in composite materials, where its characteristics, strengths, and bulk cost are intermediate between polyester and epoxy. Vinyl ester has lower resin viscosity (approx. 200 cps) than polyester (approx. 500cps) and epoxy (approx ...