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In mathematics, Hodge theory, named after W. V. D. Hodge, is a method for studying the cohomology groups of a smooth manifold M using partial differential equations.The key observation is that, given a Riemannian metric on M, every cohomology class has a canonical representative, a differential form that vanishes under the Laplacian operator of the metric.
where v is a vibrational quantum number, ω e is the harmonic wavenumber and χ e is an anharmonicity constant. When the molecule is in the gas phase, it can rotate about an axis, perpendicular to the molecular axis, passing through the centre of mass of the molecule. The rotational energy is also quantized, with term values to a first ...
Notice, however, that spherical harmonics are not functions on the sphere which are harmonic with respect to the Laplace-Beltrami operator for the standard round metric on the sphere: the only harmonic functions in this sense on the sphere are the constants, since harmonic functions satisfy the Maximum principle.
A weakly harmonic function coincides almost everywhere with a strongly harmonic function, and is in particular smooth. A weakly harmonic distribution is precisely the distribution associated to a strongly harmonic function, and so also is smooth. This is Weyl's lemma. There are other weak formulations of Laplace's equation that are often useful.
The quantum harmonic oscillator; The quantum harmonic oscillator with an applied uniform field [1] The Inverse square root potential [2] The periodic potential The particle in a lattice; The particle in a lattice of finite length [3] The Pöschl–Teller potential; The quantum pendulum; The three-dimensional potentials The rotating system The ...
The formulation relies on approximating the potential energy landscape as a series of harmonic wells. In a two state system, there will be three wells; a well for state A, an upside-down well representing the potential energy barrier, and a well for state B.
This holds for any trial φ since, by definition, the ground state wavefunction has the lowest energy, and any trial wavefunction will have energy greater than or equal to it. Proof: φ can be expanded as a linear combination of the actual eigenfunctions of the Hamiltonian (which we assume to be normalized and orthogonal): ϕ = ∑ n c n ψ n ...
Vibronic spectroscopy is a branch of molecular spectroscopy concerned with vibronic transitions: the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy.