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  2. Electrochemistry - Wikipedia

    en.wikipedia.org/wiki/Electrochemistry

    Download as PDF; Printable version ... Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference ...

  3. Standard electrode potential (data page) - Wikipedia

    en.wikipedia.org/wiki/Standard_electrode...

    The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: . Temperature 298.15 K (25.00 °C; 77.00 °F); ...

  4. Standard hydrogen electrode - Wikipedia

    en.wikipedia.org/wiki/Standard_hydrogen_electrode

    During the early development of electrochemistry, researchers used the normal hydrogen electrode as their standard for zero potential. This was convenient because it could actually be constructed by "[immersing] a platinum electrode into a solution of 1 N strong acid and [bubbling] hydrogen gas through the solution at about 1 atm pressure".

  5. Faraday efficiency - Wikipedia

    en.wikipedia.org/wiki/Faraday_efficiency

    In electrochemistry, Faraday efficiency (also called faradaic efficiency, faradaic yield, coulombic efficiency, or current efficiency) describes the efficiency with which charge is transferred in a system facilitating an electrochemical reaction.

  6. Electroanalytical methods - Wikipedia

    en.wikipedia.org/wiki/Electroanalytical_methods

    Potentiometry passively measures the potential of a solution between two electrodes, affecting the solution very little in the process. One electrode is called the reference electrode and has a constant potential, while the other one is an indicator electrode whose potential changes with the sample's composition.

  7. Auxiliary electrode - Wikipedia

    en.wikipedia.org/wiki/Auxiliary_electrode

    In electrochemistry, the auxiliary electrode, often also called the counter electrode, is an electrode used in a three-electrode electrochemical cell for voltammetric analysis or other reactions in which an electric current is expected to flow.

  8. Grotthuss mechanism - Wikipedia

    en.wikipedia.org/wiki/Grotthuss_mechanism

    Protons tunnel across a series of hydrogen bonds between hydronium ions and water molecules.. The Grotthuss mechanism (also known as proton jumping) is a model for the process by which an 'excess' proton or proton defect diffuses through the hydrogen bond network of water molecules or other hydrogen-bonded liquids through the formation and concomitant cleavage of covalent bonds involving ...

  9. Nernst equation - Wikipedia

    en.wikipedia.org/wiki/Nernst_equation

    In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...

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