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This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Phenol: 181.75 3.60 43.0 –7.27 K f [2] K b [1] Water: 100.00 0.512 0.00 –1.86 K b & K f [2] Ethyl Acetate: 77.1 [5] Acetic Anhydride: 139.0 [6] Ethylene Dichloride: 1.25 83.5 −35 [7] Acetonitrile: 0.78 81.6 −45 [8] Heptane: 98.4 [9] Isobutanol: 107.7 [10] n-Hexane: 0.66 68.7 [11] n-Butanol: 117.7 [12] Hydrochloric Acid: 84.8 [13] tert ...
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
Phenol is an organic compound appreciably soluble in water, with about 84.2 g dissolving in 1000 ml (0.895 M). Homogeneous mixtures of phenol and water at phenol to water mass ratios of ~2.6 and higher are possible. The sodium salt of phenol, sodium phenoxide, is far more water-soluble. It is a combustible solid (NFPA rating = 2).
In the table above, it can be seen that water is the most polar-solvent, followed by DMSO, and then acetonitrile. Consider the following acid dissociation equilibrium: HA ⇌ A − + H + Water, being the most polar-solvent listed above, stabilizes the ionized species to a greater extent than does DMSO or Acetonitrile.
However, the presence of the aromatic ring reduces its solubility in polar solvents such as water and ethanol. Diethyl ether has higher water solubility of 8 g per 100 mL, versus diphenyl ether, with a solubility of 0.002 g per 100 mL. [3] [4]
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