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Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. [3] The commonly known brand name of PTFE-based composition is Teflon by Chemours, [4] a spin-off from DuPont, which originally discovered the compound in 1938. [4]
A convenient, safe method for generating TFE is the pyrolysis of the sodium salt of pentafluoropropionic acid: [6]. C 2 F 5 CO 2 Na → C 2 F 4 + CO 2 + NaF. The depolymerization reaction – vacuum pyrolysis of PTFE at 650–700 °C (1,200–1,290 °F) in a quartz vessel – is a traditional laboratory synthesis of TFE.
It was determined that this material was a new-to-the-world polymer. Tests showed the substance was resistant to corrosion from most acids, bases and solvents and had better high temperature stability than any other plastic. By early 1941, a crash program was making substantial quantities of PTFE for the Manhattan Project. [1] [2] [3] [4]
The PTFE backbone interlaced with the ionic sulfonate groups gives Nafion a high chemical stability temperature (e.g. 190 °C) but a softening point in the range of 85-100 °C give it a moderate operating temperature, e.g. up to 100 °C, with additional challenges in all applications due to the loss of water above 100 °C.
PTFE has a higher melting point and is more crystalline than PCTFE, but the latter is stronger and stiffer. Though PCTFE has excellent chemical resistance, it is still less than that of PTFE. [22] PCTFE has lower viscosity, higher tensile strength and creep resistance than PTFE. [1] PCTFE is injection-moldable and extrudable, whereas PTFE is ...
Rulon is the trade name for a family of PTFE plastics produced by Saint-Gobain Performance Plastics. Rulon plastics are known for their low coefficient of friction, excellent abrasion resistance, wide range of operating temperatures, and chemical inertness. Common applications for Rulon include seals, piston rings, bearings, and electrical ...
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PTFE fiber is a chemically resistant material. It is used in woven form in certain pump packings [1] as well as in nonwoven form in hot gas bag filters for industries with corrosive exhausts. [2] [3] Because PTFE is relatively insoluble and has a very high melting point, PTFE fibers can not be fashioned from conventional melt or solution ...