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In general, MO theory can accurately predict the ground state energy of the system, the different electronic states energies of bonding and nonbonding orbitals, and magnetic and ionization properties in a straight forward manner. On the other hand, VB theory is traditionally useful for predicting bond angle and mechanism drawing.
Although hydrogen bonding is a relatively weak attraction compared to the covalent bonds within the water molecule itself, it is responsible for several of the water's physical properties. These properties include its relatively high melting and boiling point temperatures: more energy is required to break the hydrogen bonds between water molecules.
Metallic elements which are more electropositive than hydrogen, particularly the alkali metals and alkaline earth metals such as lithium, sodium, calcium, potassium and cesium displace hydrogen from water, forming hydroxides and releasing hydrogen. At high temperatures, carbon reacts with steam to form carbon monoxide and hydrogen.
An analogous effect to covalent binding is believed to occur in some nuclear systems, with the difference that the shared fermions are quarks rather than electrons. [24] High energy proton-proton scattering cross-section indicates that quark interchange of either u or d quarks is the dominant process of the nuclear force at short distance.
The strong bonding of metals in liquid form demonstrates that the energy of a metallic bond is not highly dependent on the direction of the bond; this lack of bond directionality is a direct consequence of electron delocalization, and is best understood in contrast to the directional bonding of covalent bonds. The energy of a metallic bond is ...
Some elements, such as tin and antimony, are clearly metals, but form only covalent compounds in the highest oxidation states: their aqua cations are restricted to their lower oxidation states. [1] Germanium is a semiconductor rather than a metal, but appears to form an aqua cation; similarly, hydrogen forms an aqua cation like metals, despite ...
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These hydrides are formed by all the true non-metals (except zero group elements) and the elements like Al, Ga, Sn, Pb, Bi, Po, etc., which are normally metallic in nature, i.e., this class includes the hydrides of p-block elements. In these substances the hydride bond is formally a covalent bond much like the bond made by a proton in a weak ...