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c 6 h 10 o + h 2 s + h 2 → c 6 h 11 sh + h 2 o It is also obtained by the addition of hydrogen sulfide to cyclohexene in the presence of nickel sulfide . [ 2 ]
2 c 6 h 12 + o 2 → 2 c 6 h 11 oh This process coforms cyclohexanone , and this mixture ("KA oil" for ketone-alcohol oil) is the main feedstock for the production of adipic acid . The oxidation involves radicals and the intermediacy of the hydroperoxide C 6 H 11 O 2 H. Alternatively, cyclohexanol can be produced by the hydrogenation of phenol :
Some β-hydroxyamphetamines have had their side chain extended and cyclized.Examples include certain substituted phenylmorpholines like phenmetrazine and phendimetrazine and their analogues; substituted phenylmorpholines related to bupropion like radafaxine (cyclized (2S,3S)-hydroxybupropion) and manifaxine; certain substituted aminorexes like 4-methylaminorex and 4,4'-dimethylaminorex; and ...
Chlorination of benzene under electrophilic aromatic substitution conditions (Cl 2 /FeCl 3 or Cl 2 /AlCl 3) produces chlorobenzene. Since mono chloro-de-hydrogenation deactivates the molecule against further electrophilic reactions, the reaction can be halted at one chlorine atom substitution.
Dihydroergocryptine can also be used in migraine prophylaxis, [11] as well as for the treatment of low blood pressure in elderly patients and peripheral vascular disorder. [12] More commonly, it is used in combination with two similar compounds, dihydroergocornine and dihydroergocristine. This mixture is called ergoloid or codergocrine. [13]
Cyclohexanone is produced by the oxidation of cyclohexane in air, typically using cobalt catalysts: [11]. C 6 H 12 + O 2 → (CH 2) 5 CO + H 2 O. This process forms cyclohexanol as a by-product, and this mixture, called "KA Oil" for ketone-alcohol oil, is the main feedstock for the production of adipic acid.
Cyclohexenone is also used in multi-step synthesis in the construction of polycyclic natural products. It is prochiral. With strong bases, the positions 4 and 6 (the two CH 2-groups of the carbonyl group and the C-C double bond adjacent) are deprotonated. Cyclohexenone is an in-vitro catalyst for a relatively mild decarboxylation of alpha amino ...
It is a monoterpenoid – cyclohepta-2,4,6-trien-1-one substituted by a hydroxy group at position 2 and an isopropyl group at position 4. [26] [27] [28] It is a enol and a cyclic ketone. It derives from a hydride of a cyclohepta-1,3,5-triene. Thujaplicins are soluble in organic solvents and aqueous buffers. [2]
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