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Anhydrous ferric hydroxide occurs in the nature as the exceedingly rare mineral bernalite, Fe(OH) 3 ·nH 2 O (n = 0.0–0.25). [4] [5] Iron oxyhydroxides, FeOOH, are much more common and occur naturally as structurally different minerals (polymorphs) denoted by the Greek letters α, β, γ and δ.
All the iron(II) sulfates dissolve in water to give the same aquo complex [Fe(H 2 O) 6] 2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas ...
The various crystalline forms of Fe 2 (SO 4) 3 (H 2 O) n are well-defined, often by X-ray crystallography. The nature of the aqueous solutions is often less certain, but aquo-hydroxo complexes such as [Fe(H 2 O) 6] 3+ and [Fe(H 2 O) 5 (OH)] 2+ are often assumed. [4] Regardless, all such solids and solutions feature ferric ions, each with five ...
Mixtures of Fe 2+ and H 2 O 2 are called Fenton reagent. If Fe 2+ is replaced by Fe 3+ , it is called Fenton-like reagent. Numerous transition metal ions and their complexes in their lower oxidation states (L m M n+ ) were found to have the oxidative features of the Fenton reagent, and, therefore, the mixtures of these metal compounds with H 2 ...
Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O. Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate. It is a common laboratory reagent because it is readily crystallized, and crystals resist oxidation ...
Ammonium iron(III) sulfate, NH 4 Fe(SO 4) 2 ·12 H 2 O, or NH 4 [Fe(H 2 O) 6](SO 4) 2 ·6 H 2 O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO 4) 2 · 12 H 2 O. [2] It has the appearance of weakly violet, octahedrical crystals.
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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.