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The structure of sodium oxide has been determined by X-ray crystallography.Most alkali metal oxides M 2 O (M = Li, Na, K, Rb) crystallise in the antifluorite structure.In this motif the positions of the anions and cations are reversed relative to their positions in CaF 2, with sodium ions tetrahedrally coordinated to 4 oxide ions and oxide cubically coordinated to 8 sodium ions.
Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. As a result, sodium usually forms ionic compounds involving the Na + cation. [1] Sodium is a reactive alkali metal and is much more stable in ionic compounds. It can also form intermetallic compounds and organosodium compounds.
The −1 occurs because each carbon is bonded to one hydrogen atom (a less electronegative element), and the − 1 / 5 because the total ionic charge of −1 is divided among five equivalent carbons. Again this can be described as a resonance hybrid of five equivalent structures, each having four carbons with oxidation state −1 and ...
The strength of the M-O bond tends to increase with the charge and decrease as the size of the metal ion increases. In fact there is a very good linear correlation between hydration enthalpy and the ratio of charge squared to ionic radius, z 2 /r. [4] For ions in solution Shannon's "effective ionic radius" is the measure most often used. [5]
Sodium methoxide is prepared by treating methanol with sodium: 2 Na + 2 CH 3 OH → 2 CH 3 ONa + H 2. The reaction is so exothermic that ignition is possible. The resulting solution, which is colorless, is often used as a source of sodium methoxide, but the pure material can be isolated by evaporation followed by heating to remove residual methanol.
Sodium cobalt oxide, also called sodium cobaltate, is any of a range of compounds of sodium, cobalt, and oxygen with the general formula Na x CoO 2 for 0 < x ≤ 1. The name is also used for hydrated forms of those compounds, Na x CoO 2 ·y H 2 O. The anhydrous compound was first synthesized in the 1970s. [2]
Sodium superoxide is the inorganic compound with the formula Na O 2. [1] This yellow-orange solid is a salt of the superoxide anion. It is an intermediate in the oxidation of sodium by oxygen.
Extreme acidity, heat, and dehydrating conditions are usually required. Other hydrocarbon oxonium ions are formed by protonation or alkylation of alcohols or ethers (R−C− + −R 1 R 2). Secondary oxonium ions have the formula R 2 OH +, an example being protonated ethers. Tertiary oxonium ions have the formula R 3 O +, an example being ...