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HDPE is known for its high strength-to-density ratio. [4] The density of HDPE ranges from 930 to 970 kg/m 3. [5] Although the density of HDPE is only marginally higher than that of low-density polyethylene, HDPE has little branching, giving it stronger intermolecular forces and tensile strength (38 MPa versus 21 MPa) than LDPE. [6]
The high molecular weight makes it a very tough material, but results in less efficient packing of the chains into the crystal structure as evidenced by densities of less than high-density polyethylene (for example, 0.930–0.935 g/cm 3). UHMWPE can be made through any catalyst technology, although Ziegler catalysts are most common.
The heat deflection temperature or heat distortion temperature (HDT, HDTUL, or DTUL) is the temperature at which a polymer or plastic sample deforms under a specified load. [1] This property of a given plastic material is applied in many aspects of product design, engineering and manufacture of products using thermoplastic components.
The most commonly produced plastic consumer products include packaging made from LDPE (e.g. bags, containers, food packaging film), containers made from HDPE (e.g. milk bottles, shampoo bottles, ice cream tubs), and PET (e.g. bottles for water and other drinks). Together these products account for around 36% of plastics use in the world.
The shelf life of pasteurized milk in HDPE bottles and LDPE pouches has been determined to be between 10 and 21 days when stored at 4–8 °C. Other factors such as light and temperature abuse have effects. Shelf life can be extended by ultrapasteurisation and aseptic processing. [6] [7]
Brittleness can be decreased with the addition of plasticizers, which increases the mobility of amorphous chain segments to effectively lower the glass transition temperature. Modification of the polymer through copolymerization or through the addition of non-reactive side chains to monomers before polymerization can also lower it.
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These molecules are several orders of magnitude longer than those of familiar high-density polyethylene (HDPE) due to a synthesis process based on metallocene catalysts, resulting in UHMWPE molecules typically having 100,000 to 250,000 monomer units per molecule each compared to HDPE's 700 to 1,800 monomers.