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Calcite, like most carbonates, dissolves in acids by the following reaction CaCO 3 + 2 H + → Ca 2+ + H 2 O + CO 2. The carbon dioxide released by this reaction produces a characteristic effervescence when a calcite sample is treated with an acid. Due to its acidity, carbon dioxide has a slight solubilizing effect on calcite. The overall ...
Carbon dioxide dissolves in and reacts with seawater to form carbonic acid. Subsequent reactions then produce carbonate (CO 3 2−), bicarbonate (HCO 3 −), and hydrogen (H +) ions. Carbonate and bicarbonate are also deposited into the global ocean by rivers through the weathering of rock formations.
Precipitated calcium carbonate, made by dropping calcium oxide into water, is used by itself or with additives as a white paint, known as whitewashing. [49] [50] Calcium carbonate is added to a wide range of trade and do it yourself adhesives, sealants, and decorating fillers. [46] Ceramic tile adhesives typically contain 70% to 80% limestone.
The alternation of calcite and aragonite seas through geologic time A calcite sea is a sea in which low-magnesium calcite is the primary inorganic marine calcium carbonate precipitate. An aragonite sea is the alternate seawater chemistry in which aragonite and high-magnesium calcite are the primary inorganic carbonate precipitates.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
Simply because a substance does not readily dissolve does not make it a weak electrolyte. Acetic acid (CH 3 COOH) and ammonium (NH + 4) are good examples. Acetic acid is extremely soluble in water, but most of the compound dissolves into molecules, rendering it a weak electrolyte. Weak bases and weak acids are generally weak electrolytes.
The heat energy delivered to the gypsum at this time (the heat of hydration) tends to go into driving off water (as water vapor) rather than increasing the temperature of the mineral, which rises slowly until the water is gone, then increases more rapidly. The equation for the partial dehydration is: