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Robert Wilhelm Eberhard Bunsen (German:; 30 March 1811 [a] – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. [11] The Bunsen–Kirchhoff Award for spectroscopy is named after Bunsen and Kirchhoff.
Spectroscope of Kirchhoff and Bunsen. The systematic attribution of spectra to chemical elements began in the 1860s with the work of German physicists Robert Bunsen and Gustav Kirchhoff, [30] who found that Fraunhofer lines correspond to emission spectral lines observed in laboratory light sources. This laid way for spectrochemical analysis in ...
[7] [8] He proposed his law of thermal radiation in 1859, and gave a proof in 1861. Together Kirchhoff and Bunsen invented the spectroscope, which Kirchhoff used to pioneer the identification of the elements in the Sun, showing in 1859 that the Sun contains sodium. He and Bunsen discovered caesium and rubidium in 1861. [9]
They discovered caesium by its two blue emission lines in a sample of Dürkheim mineral water. [130] The pure metal was eventually isolated in 1882 by Setterberg. [131] 37 Rubidium: 1861 R. Bunsen and G. R. Kirchhoff: 1863 R. Bunsen Bunsen and Kirchhoff discovered it just a few months after caesium, by observing new spectral lines in the ...
In 1860, the unexpected appearance of sky-blue and dark red was observed in spectral emissions by Robert Bunsen and Gustav Kirchhoff, leading to the discovery of two alkali metals, caesium and rubidium (dark red). [4] [1] Today, this low-cost method is used in secondary education to teach students to detect metals in samples qualitatively. [2]
Bunsen was joined in his research by Gustav Kirchhoff. Kirchhoff used the concept of the dispersion of white light by a prism in the invention of the spectroscope , a device with a prism at its centre which split the light from Bunsen's flames into distinct bands of its constituent colours – the element's spectral lines .
1860–61: Discovery of caesium and rubidium by Robert Bunsen and Gustav Kirchhoff [139] 1860: Erlenmeyer flask by Emil Erlenmeyer [ 140 ] 1863–64: Discovery of indium by Ferdinand Reich and Hieronymous Theodor Richter [ 141 ] [ 142 ] [ 143 ]
Gustav Robert Kirchhoff and Robert Bunsen discovered the application of spectroscopes to chemical analysis and used this approach to discover caesium and rubidium. [6] [7] Kirchhoff and Bunsen's analysis also enabled a chemical explanation of stellar spectra, including Fraunhofer lines. [8]