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4-Methylpyridine is both isolated from coal tar and is synthesized industrially. It forms via the reaction of acetaldehyde and ammonia in the presence of an oxide catalyst. The method also affords some 2-methylpyridine. 4-Methylpyridine is of little intrinsic value but is a precursor to other commercially significant species, often of medicinal ...
For example, reduction with lithium aluminium hydride yields a mixture of 1,4-dihydropyridine, 1,2-dihydropyridine, and 2,5-dihydropyridine. [102] Selective synthesis of 1,4-dihydropyridine is achieved in the presence of organometallic complexes of magnesium and zinc , [ 103 ] and (Δ3,4)-tetrahydropyridine is obtained by electrochemical ...
Download as PDF; Printable version; In other projects Wikidata item; Appearance. ... 4-Methylpyridine This page was last edited on 28 August 2022, at 16:29 ...
trans-[MCl 2 (pyridine) 4] n+ is a common type of transition metal pyridine complex. Chloro(pyridine)cobaloxime. Crabtree's catalyst.. Owing to the relatively wide C-N-C angle, the 2,6-hydrogen atoms interfere with the formation of [M(py) 6] z complexes.
The Chichibabin pyridine synthesis (/ ˈ tʃ iː tʃ iː ˌ b eɪ b iː n /) is a method for synthesizing pyridine rings. The reaction involves the condensation reaction of aldehydes, ketones, α,β-Unsaturated carbonyl compounds, or any combination of the above, with ammonia. [1]
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PhIP (2-Amino-1-methyl-6-phenylimidazo[4,5-b]pyridine) is one of the most abundant heterocyclic amines (HCAs) in cooked meat. PhIP is formed at high temperatures from the reaction between creatine or creatinine (found in muscle meats), amino acids , and sugar.