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The Mozingo reduction, also known as Mozingo reaction or thioketal reduction, is a chemical reaction capable of fully reducing a ketone or aldehyde to the corresponding alkane via a dithioacetal. [1] [2] The reaction scheme is as follows: [3]
This is a list of notable academic journals about nursing.. AACN Advanced Critical Care; AACN Nursing Scan in Critical Care; Advances in Neonatal Care; American Journal of Critical Care
The overall combined transformation of an aldehyde to an alkyne by this method is named after its developers, American chemists Elias James Corey and Philip L. Fuchs. The Corey–Fuchs reaction By suitable choice of base, it is often possible to stop the reaction at the 1-bromoalkyne, a useful functional group for further transformation.
Aldehydes and ketones can be reduced respectively to primary and secondary alcohols. In deoxygenation, the alcohol group can be further reduced and removed altogether by replacement with H. Two broad strategies exist for carbonyl reduction. One method, which is favored in industry, uses hydrogen as the reductant.
The mechanism of reductions of aldehydes and ketones by samarium(II) iodide is based primarily on mechanisms elucidated for similar one-electron reducing agents. [12] Upon single-electron transfer, a ketyl dimer iv forms. In the absence of protic solvent, this dimer collapses to form 1,2-diols.
The journal was established in 1900 as the official journal of the Associated Alumnae of Trained Nurses of the United States which later became the American Nurses Association. [3] Isabel Hampton Robb, Lavinia Dock, Mary E. P. Davis and Sophia Palmer are credited with founding the journal, [4] the latter serving as the first editor. [5]
The Journal of Research in Nursing is a bimonthly peer-reviewed nursing journal that covers the field of nursing. The editors-in-chief are Andree Le May (University of Southampton) and Ann McMahon. The journal was established in 1996 and is published by SAGE Publications.
Dimethyl sulfide (Me 2 S) is treated with N-chlorosuccinimide (NCS), resulting in formation of an "active DMSO" species that is used for the activation of the alcohol. . Addition of triethylamine to the activated alcohol leads to its oxidation to aldehyde or ketone and generation of dimethyl