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MMA is a raw material for the manufacture of other methacrylates. These derivatives include ethyl methacrylate (EMA), butyl methacrylate (BMA) and 2-ethyl hexyl methacrylate (2-EHMA). Methacrylic acid (MAA) is used as a chemical intermediate as well as in the manufacture of coating polymers, construction chemicals and textile applications.
Methacrylic acid, abbreviated MAA, is an organic compound with the formula CH 2 =C(CH 3)CO 2 H. This colorless, viscous liquid is a carboxylic acid with an acrid unpleasant odor.
Purified monomers stored at ambient temperatures are of less risk of polymerising and as such the most highly reactive inhibitors are rarely used at this stage. In general compounds are chosen which can be easily removed immediately prior to industrial polymerisation to make plastics.
The monomer is a viscous liquid with a pungent odour. The first polymeric form of methacrylic acid was described in 1880 by Engelhorn and Fittig. The use of high purity monomers is required for proper polymerization conditions and therefore it is necessary to remove any inhibitors by extraction (phenolic inhibitors) or via distillation. [ 2 ]
AMPS is made by the Ritter reaction of acrylonitrile and isobutylene in the presence of sulfuric acid and water. [2] The recent patent literature [3] describes batch and continuous processes that produce AMPS in high purity (to 99.7%) and improved yield (up to 89%, based on isobutene) with the addition of liquid isobutene to an acrylonitrile / sulfuric acid / phosphoric acid mixture at 40°C.
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In polymer chemistry, suspension polymerization is a heterogeneous radical polymerization process that uses mechanical agitation to mix a monomer or mixture of monomers in a liquid phase, such as water, while the monomers polymerize, forming spheres of polymer. [2] The monomer droplets (size of the order 10-1000 μm) are suspended in the liquid ...
An example of an ionomer, with carboxylate groups bound to a zinc cation. An ionomer (/ ˌ aɪ ˈ ɑː n ə m ər /) (iono-+ -mer) is a polymer composed of repeat units of both electrically neutral repeating units and ionized units covalently bonded to the polymer backbone as pendant group moieties.