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  2. Multiplicity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Multiplicity_(chemistry)

    When S > L there are only 2L+1 orientations of total angular momentum possible, ranging from S+L to S-L. [2] [3] The ground state of the nitrogen atom is a 4 S state, for which 2S + 1 = 4 in a quartet state, S = 3/2 due to three unpaired electrons. For an S state, L = 0 so that J can only be 3/2 and there is only one level even though the ...

  3. Hund's rule of maximum multiplicity - Wikipedia

    en.wikipedia.org/wiki/Hund's_Rule_of_Maximum...

    For example, the nitrogen atom ground state has three unpaired electrons of parallel spin, so that the total spin is 3/2 and the multiplicity is 4. The lower energy and increased stability of the atom arise because the high-spin state has unpaired electrons of parallel spin, which must reside in different spatial orbitals according to the Pauli ...

  4. Unpaired electron - Wikipedia

    en.wikipedia.org/wiki/Unpaired_electron

    The ions with the largest number of unpaired electrons are Gd 3+ and Cm 3+ with seven unpaired electrons. An unpaired electron has a magnetic dipole moment, while an electron pair has no dipole moment because the two electrons have opposite spins so their magnetic dipole fields are in opposite directions and cancel. Thus an atom with unpaired ...

  5. Paschen's law - Wikipedia

    en.wikipedia.org/wiki/Paschen's_law

    where is the breakdown voltage in volts, is the pressure in pascals, is the gap distance in meters, is the secondary-electron-emission coefficient (the number of secondary electrons produced per incident positive ion), is the saturation ionization in the gas at a particular / (electric field/pressure), and is related to the excitation and ...

  6. Nitrogen - Wikipedia

    en.wikipedia.org/wiki/Nitrogen

    Nitrogen is the most common pure element in the earth, making up 78.1% of the volume of the atmosphere [9] (75.5% by mass), around 3.89 million gigatonnes (3.89 × 10 18 kg). Despite this, it is not very abundant in Earth's crust, making up somewhere around 19 parts per million of this, on par with niobium , gallium , and lithium .

  7. Radical (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Radical_(chemistry)

    Lewis dot structure of a Hydroxide ion compared to a hydroxyl radical. In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1] [2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most ...

  8. Exchange interaction - Wikipedia

    en.wikipedia.org/wiki/Exchange_interaction

    By contrast, an isolated Ni atom (electron configuration = 3d 8 4s 2) in a cubic crystal field will have two unpaired electrons of the same spin (hence, =) and would thus be expected to have in the localized electron model a total spin magnetic moment of = (but the measured spin-only magnetic moment along one axis, the physical observable, will ...

  9. Hyperfine structure - Wikipedia

    en.wikipedia.org/wiki/Hyperfine_structure

    In atomic physics, hyperfine structure is defined by small shifts in otherwise degenerate electronic energy levels and the resulting splittings in those electronic energy levels of atoms, molecules, and ions, due to electromagnetic multipole interaction between the nucleus and electron clouds.

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