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The Experiments on the relative motion of the earth and ether have been completed and the result decidedly negative. The expected deviation of the interference fringes from the zero should have been 0.40 of a fringe – the maximum displacement was 0.02 and the average much less than 0.01 – and then not in the right place.
According to ancient and medieval science, aether (/ ˈ iː θ ər /, alternative spellings include æther, aither, and ether), also known as the fifth element or quintessence, is the material that fills the region of the universe beyond the terrestrial sphere. [1]
This term is often used in organic chemistry. For example, from the word ether , referring to an oxygen-containing compound having the general chemical structure R−O−R′ , where R and R′ are organic functional groups and O is an oxygen atom, comes the word thioether , which refers to an analogous compound with the general structure R−S ...
A typical example of the first group is the solvent and anaesthetic diethyl ether, commonly referred to simply as "ether" (CH 3 −CH 2 −O−CH 2 −CH 3). Ethers are common in organic chemistry and even more prevalent in biochemistry , as they are common linkages in carbohydrates and lignin .
In the 19th century, luminiferous aether (or ether), meaning light-bearing aether, was a theorized medium for the propagation of light. James Clerk Maxwell developed a model to explain electric and magnetic phenomena using the aether, a model that led to what are now called Maxwell's equations and the understanding that light is an ...
Alkenes can be made from alcohols by dehydration. This conversion, among others, is used in converting biomass to liquid fuels. [2] The conversion of ethanol to ethylene is a fundamental example: [3] [4] CH 3 CH 2 OH → H 2 C=CH 2 + H 2 O. The reaction is accelerated by acid catalysts such as sulfuric acid and certain zeolites.
In 1962, Edwards and Pearson (the latter of HSAB theory) introduced the phrase alpha effect for this anomaly. He offered the suggestion that the effect was caused by a transition state (TS) stabilization effect: on entering the TS the free electron pair on the nucleophile moves away from the nucleus, causing a partial positive charge which can be stabilized by an adjacent lone pair as for ...
The term is mainly used in coordination chemistry. The template effects emphasizes the pre-organization provided by the coordination sphere, although the coordination modifies the electronic properties (acidity, electrophilicity, etc.) of ligands. [1] An early example is the dialkylation of a nickel dithiolate: [2]