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In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
At pH = 7, when [ H +] = 10 −7 M, the reduction potential of H + differs from zero because it depends on pH. Solving the Nernst equation for the half-reaction of reduction of two protons into hydrogen gas gives: 2 H + + 2 e − ⇌ H 2
Variations from these ideal conditions affect measured voltage via the Nernst equation. Electrode potentials of successive elementary half-reactions cannot be directly added. However, the corresponding Gibbs free energy changes (∆ G °) must satisfy
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
The polarity of the standard electrode potential provides information about the relative reduction potential of the electrode compared to the SHE. If the electrode has a positive potential with respect to the SHE, then that means it is a strongly reducing electrode which forces the SHE to be the anode (an example is Cu in aqueous CuSO 4 with a ...
3) Acid solution with an activity of H + = 1 mol/L, 4) Hydroseal for prevention of oxygen interference, 5) Reservoir via which the second half-element of the galvanic cell should be attached. The connection can be direct, through a narrow tube to reduce mixing, or through a salt bridge, depending on the other electrode and solution. This ...
Siméon Denis Poisson. Poisson's equation is an elliptic partial differential equation of broad utility in theoretical physics.For example, the solution to Poisson's equation is the potential field caused by a given electric charge or mass density distribution; with the potential field known, one can then calculate the corresponding electrostatic or gravitational (force) field.
The electric potential also varies with temperature, concentration and pressure. Since the oxidation potential of a half-reaction is the negative of the reduction potential in a redox reaction, it is sufficient to calculate either one of the potentials. Therefore, standard electrode potential is commonly written as standard reduction potential.