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The thiocarbonate moiety can be functionalized at the R-group for end group analysis. The end group is a result of the propagation of chain-transfer agents during the free-radical polymerization process. The end groups can subsequently be modified by the reaction of the thiocarbonylthio compounds with nucleophiles and ionic reducing agents. [11]
Example: 2,2,3-trimethyl- . If there are both double bonds and triple bonds, "en" (double bond) is written before "yne" (triple bond). When the main functional group is a terminal functional group (a group which can exist only at the end of a chain, like formyl and carboxyl groups), there is no need to number it.
IUPAC Polymer Nomenclature are standardized naming conventions for polymers set by the International Union of Pure ... End-groups are described with α- and ω-, e.g ...
This naming method generally follows established IUPAC organic nomenclature. Hydrides of the main group elements (groups 13–17) are given the base name ending with -ane, e.g. borane (B H 3), oxidane (H 2 O), phosphane (P H 3) (Although the name phosphine is also in common use, it is not recommended by
In organic chemistry, a vinyl group (abbr. Vi; [1] IUPAC name: ethenyl group [2]) is a functional group with the formula −CH=CH 2. It is the ethylene (IUPAC name: ethene) molecule (H 2 C=CH 2) with one fewer hydrogen atom. The name is also used for any compound containing that group, namely R−CH=CH 2 where R is any other group of atoms.
In 1919, a group of chemists created the IUPAC with this idea, as well as the purpose of unionizing scientists and strengthening the international trade of science. IUPAC celebrated its 100th anniversary in 2019 and continues to regulate scientific terminology today.
The group numberings with Roman numbers and "A" and "B" suffixes (like VIIA, VIII) should not be used, as they are outdated and ambiguous. For example, in the CAS scheme "group VIIB" denotes manganese group (group 7), while in the old IUPAC scheme it denotes halogen group (group 17). If they are used at all, context should clarify (disambiguate ...
In organic chemistry, a substituent is one or a group of atoms that replaces (one or more) atoms, thereby becoming a moiety in the resultant (new) molecule. [1] ( In organic chemistry and biochemistry, the terms substituent and functional group, as well as side chain and pendant group, are used almost interchangeably to describe those branches from the parent structure, [2] though certain ...