Search results
Results from the WOW.Com Content Network
Salt metathesis is a common technique for exchanging counterions. The choice of reactants is guided by a solubility chart or lattice energy. HSAB theory can also be used to predict the products of a metathesis reaction. Salt metathesis is often employed to obtain salts that are soluble in organic solvents.
Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate is an anion with chemical formula [{3,5-(CF 3) 2 C 6 H 3} 4 B] −, which is commonly abbreviated as [BAr F 4] −, indicating the presence of fluorinated aryl (Ar F) groups. It is sometimes referred to as Kobayashi's anion in honour of Hiroshi Kobayashi who led the team that first synthesised it. [1]
RC≡W(O-t-Bu) 3 can react with normal alkynes for metathesis reactions and also with terminal alkynes for both metathesis reactions and polymerizations. [ 6 ] Besides simple metathesis reactions, W 2 (O- t -Bu) 6 also reacts with 3-hexyne in a 1:1 molar ratio to form a triangular tritungsten complex compound [W 3 (O- t -Bu) 5 (μ-O)(μ-CEt)O ...
Using salt metathesis reactions, nitrite, azide, and other small inorganic anions can be obtained with [(Ph 3 P) 2 N] + cations. The resulting salts [(Ph 3 P) 2 N] + NO − 2, [(Ph 3 P) 2 N] + N − 3, etc. are soluble in polar organic solvents. [(Ph 3 P) 2 N] + forms crystalline salts with a range of anions that are otherwise difficult to ...
Tetraethylammonium (TEA) is a quaternary ammonium cation with the chemical formula [Et 4 N] +, consisting of four ethyl groups (−C 2 H 5, denoted Et) attached to a central nitrogen atom. It is a counterion used in the research laboratory to prepare lipophilic salts of inorganic anions.
The compound is prepared by the salt metathesis reaction of potassium iodide and potassium tetrachloroplatinate: [3] K 2 PtCl 4 + 4 KI → K 2 PtI 4 + 4 KCl Potassium tetraiodoplatinate is a precursor to the anticancer drug cisplatin .
Metathesis (linguistics), alteration of the order of phonemes within a word Quantitative metathesis , exchange of long and short roles, without changing order of vowel sounds Chemical change in which a pair of molecules exchange electronic patterns of bonding
Salt metathesis reaction; Salt-free reduction; Scavenger resin; Screaming jelly babies; SEA Native Peptide Ligation; Self-assembling peptide; Semiclassical transition state theory; Shiina esterification; Side reaction; Single displacement reaction; Small molecule sensors; Solid-state reaction route; Spin-forbidden reactions; Stripping reaction ...