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This lists the character tables for the more common molecular point groups used in the study of molecular symmetry.These tables are based on the group-theoretical treatment of the symmetry operations present in common molecules, and are useful in molecular spectroscopy and quantum chemistry.
The irreducible complex characters of a finite group form a character table which encodes much useful information about the group G in a concise form. Each row is labelled by an irreducible character and the entries in the row are the values of that character on any representative of the respective conjugacy class of G (because characters are class functions).
The irreducible complex characters of a finite group form a character table which encodes much useful information about the group G in a compact form. Each row is labelled by an irreducible representation and the entries in the row are the characters of the representation on the respective conjugacy class of G .
Hans Bethe used characters of point group operations in his study of ligand field theory in 1929, and Eugene Wigner used group theory to explain the selection rules of atomic spectroscopy. [13] The first character tables were compiled by László Tisza (1933), in connection to vibrational spectra.
In mathematics, a character group is the group of representations of an abelian group by complex-valued functions. These functions can be thought of as one-dimensional matrix representations and so are special cases of the group characters that arise in the related context of character theory .
The space of complex-valued class functions of a finite group G has a natural inner product: , := | | () ¯ where () ¯ denotes the complex conjugate of the value of on g.With respect to this inner product, the irreducible characters form an orthonormal basis for the space of class functions, and this yields the orthogonality relation for the rows of the character table:
The ATLAS of Finite Groups, often simply known as the ATLAS, is a group theory book by John Horton Conway, Robert Turner Curtis, Simon Phillips Norton, Richard Alan Parker and Robert Arnott Wilson (with computational assistance from J. G. Thackray), published in December 1985 by Oxford University Press and reprinted with corrections in 2003 (ISBN 978-0-19-853199-9).
In geometry, a point group in three dimensions is an isometry group in three dimensions that leaves the origin fixed, or correspondingly, an isometry group of a sphere.It is a subgroup of the orthogonal group O(3), the group of all isometries that leave the origin fixed, or correspondingly, the group of orthogonal matrices.