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The oxygen ions form a nearly hexagonal close-packed structure with the aluminium ions filling two-thirds of the octahedral interstices. Each Al 3+ center is octahedral . In terms of its crystallography , corundum adopts a trigonal Bravais lattice with a space group of R 3 c (number 167 in the International Tables).
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
This is exemplified best in the case of the hydrogen fluoride molecule, the dot-and-cross diagram of which is shown on the right. Here, the Lewis structure drawn on the left of the image is compared with the LDQ line structure on the right of the image.
Al 2 O commonly exists as a gas, since the solid state is not stable at room temperature and is only stable between 1050 and 1600 °C. Aluminium(I) oxide is formed by heating Al and Al 2 O 3 in a vacuum while in the presence of SiO 2 and C, and only by condensing the products. [2]
A diatomic molecular orbital diagram is used to understand the bonding of a diatomic molecule. MO diagrams can be used to deduce magnetic properties of a molecule and how they change with ionization. They also give insight to the bond order of the molecule, how many bonds are shared between the two atoms. [12]
The only stable chalcogenides under normal conditions are aluminium sulfide (Al 2 S 3), selenide (Al 2 Se 3), and telluride (Al 2 Te 3). All three are prepared by direct reaction of their elements at about 1,000 °C (1,832 °F) and quickly hydrolyse completely in water to yield aluminium hydroxide and the respective hydrogen chalcogenide.
[13] [14] Despite this, the human body produces small amounts of this sulfide and its mineral salts, and uses it as a signalling molecule. [15] Hydrogen sulfide is often produced from the microbial breakdown of organic matter in the absence of oxygen, such as in swamps and sewers; this process is commonly known as anaerobic digestion, which is ...
Aluminium sulfide is a chemical compound with the formula Al 2 S 3. This colorless species has an interesting structural chemistry, existing in several forms. The material is sensitive to moisture, hydrolyzing to hydrated aluminium oxides/hydroxides. [1] This can begin when the sulfide is exposed to the atmosphere.