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The most important TMA compound from a pharmacological standpoint is TMA-2, as this isomer has been much more widely used as a recreational drug and sold on the grey market as a so-called research chemical; TMA (sometimes referred to as "mescalamphetamine" or TMA-1) and TMA-6 have also been used in this way to a lesser extent.
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The reduction of TMAO to TMA, catalyzed by TMAO reductase, as part of the electron transport chain follows the following reaction: NADH + H + + trimethylamine N-oxide ⇌ {\displaystyle \rightleftharpoons } NAD + + trimethylamine + H 2 O However, both the R. denitrificans and E. coli enzymes can accept electrons from cytochromes : [ 8 ]
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2,5-Dimethoxy-4-iodoamphetamine (DOI) is a psychedelic drug and a substituted amphetamine. Unlike many other substituted amphetamines, however, it is not primarily a stimulant . [ 3 ] DOI has a stereocenter and R -(−)-DOI is the more active stereoisomer .
[1] [2] It was first synthesized in 1970 [1] and was encountered as a street drug in Italy in the same decade. [3] MMA was largely forgotten until being reassayed by David E. Nichols as a non-neurotoxic MDMA analogue in 1991, [2] and has subsequently been sold as a designer drug on the internet since the late 2000s. [citation needed]
Al 2 Me 6 + 3 H 2 O → Al 2 O 3 + 6 CH 4. Under controlled conditions, the reaction can be stopped to give methylaluminoxane: AlMe 3 + H 2 O → 1/n [AlMeO] n + 2 CH 4. Alcoholysis and aminolysis reactions proceed comparably. For example, dimethylamine gives the dialuminium diamide dimer: [7] 2 AlMe 3 + 2 HNMe 2 → [AlMe 2 NMe 2] 2 + 2 CH 4
N-Methyl-2-methoxy-4,5-methylenedioxyamphetamine (methyl-MMDA-2; 6-methoxy-MDMA) is a psychedelic drug of the amphetamine class. [1] It is the N-methylated derivative of MMDA-2, and it is also an analog of MDMA and 6-methyl-MDA. [1] Methyl-MMDA-2 was first synthesized by Alexander Shulgin and was described in his book PiHKAL.