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Its chemical formula is usually expressed as Pb(CH 3 COO) 2 or Pb(OAc) 2, where Ac represents the acetyl group. Like many other lead compounds, it causes lead poisoning. Lead acetate is soluble in water and glycerin. With water it forms the trihydrate, Pb(OAc) 2 ·3H 2 O, a colourless or white efflorescent monoclinic crystalline substance.
It is typically prepared by treating of red lead with acetic acid and acetic anhydride (Ac 2 O), which absorbs water. The net reaction is shown: [4] [5] Pb 3 O 4 + 4 Ac 2 O → Pb(OAc) 4 + 2 Pb(OAc) 2. The remaining lead(II) acetate can be partially oxidized to the tetraacetate by Cl 2, with a PbCl 2 by-product: 2 Pb(OAc) 2 + Cl 2 → Pb(OAc) 4 ...
A numeric character reference refers to a character by its Universal Character Set/Unicode code point, and a character entity reference refers to a character by a predefined name. A numeric character reference uses the format &#nnnn; or &#xhhhh; where nnnn is the code point in decimal form, and hhhh is the code point in hexadecimal form.
Iodine-based reagents such as periodic acid (HIO 4) and (diacetoxyiodo)benzene (PhI(OAc) 2) are commonly used. [3] Another reagent is lead tetraacetate (Pb(OAc) 4). [4] These I- and Pb-based methods are called the Malaprade reaction and Criegee oxidation, respectively. The former is favored for aqueous solutions, the latter for nonaqueous ...
Palladium(II) acetate is a chemical compound of palladium described by the formula [Pd(O 2 CCH 3) 2] n, abbreviated [Pd(OAc) 2] n. It is more reactive than the analogous platinum compound. Depending on the value of n, the compound is soluble in many organic solvents and is commonly used as a catalyst for organic reactions. [2]
The Cr 2 (OAc) 4 (H 2 O) 2 molecule contains two atoms of chromium, two ligated molecules of water, and four acetate bridging ligands.The coordination environment around each chromium atom consists of four oxygen atoms (one from each acetate ligand) in a square, one water molecule (in an axial position), and the other chromium atom (opposite the water molecule), giving each chromium centre an ...
The anhydrous material and dihydrate Mn(CH 3 CO 2) 2 ·2H 2 O are coordination polymers. The dihydrate has been characterized by X-ray crystallography. Each Mn(II) center is surrounded by six oxygen centers provided by aquo ligands and acetates. Subunit of the structure of the dihydrate of manganese(II) acetate. [5]
The Hg 2+ center binds to alkenes, inducing the addition of hydroxide and alkoxide. For example, treatment of methyl acrylate with mercuric acetate in methanol gives an α-mercuri ester: [6] Hg(OAc) 2 + CH 2 =CHCO 2 CH 3 + CH 3 OH → CH 3 OCH 2 CH(HgOAc)CO 2 CH 3 + HOAc. Exploiting the high affinity of mercury(II) for sulfur ligands, Hg(OAc) 2 ...