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The reagent is an alkaline solution of potassium permanganate. Reaction with double or triple bonds (R 2 C=CR 2 or R−C≡C−R) causes the color to fade from purplish-pink to brown. Aldehydes and formic acid (and formates) also give a positive test. [43] The test is antiquated. Baeyer's reagent reaction
The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: . Temperature 298.15 K (25.00 °C; 77.00 °F); ...
Potassium permanganate will decompose into potassium manganate, manganese dioxide and oxygen gas: 2 KMnO 4 → K 2 MnO 4 + MnO 2 + O 2 This reaction is a laboratory method to prepare oxygen, but produces samples of potassium manganate contaminated with MnO 2 .
For instance, potassium permanganate decomposes at 230 °C to potassium manganate and manganese dioxide, releasing oxygen gas: 2 KMnO 4 → K 2 MnO 4 + MnO 2 + O 2 A permanganate can oxidize an amine to a nitro compound , [ 7 ] [ 8 ] an alcohol to a ketone , [ 9 ] an aldehyde to a carboxylic acid , [ 10 ] [ 11 ] a terminal alkene to a ...
ref T c (K) T c (°C) P c (MPa) P c (other) V c (cm 3 /mol) ρ c (g/cm 3) ; 1 H hydrogen; use: 32.97: −240.18: 1.293: CRC.a: 32.97: −240.18: 1.293: 65: KAL: 33.2: 1.297: 65.0: SMI: −239.9: 13.2 kgf/cm 2: 0.0310 1 H hydrogen (equilibrium)
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Ki-iti Horai, Thermal conductivity of Rock Forming minerals, Journal of Geophysical Research, Volume 76, Issue 5, pages 1278 — 1308, February 10, 1971. Solidity ≡ The ratio of the volume of solid to the bulk volume, or the ratio of bulk density to solid grain density, d B /d G. Robertson, p. 5. Beryllium oxide: 218 [37]-260 [47]-300 [47]
The chemical chameleon reaction shows the process in reverse, by reducing violet potassium permanganate first to green potassium manganate and eventually to brown manganese dioxide: [1] [2] [5] KMnO 4 (violet) → K 2 MnO 4 (green) → MnO 2 (brown/yellow suspension) Blue potassium hypomanganate may also form as an intermediate. [6]