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Aziridine is an organic compound consisting of the three-membered heterocycle C 2 H 5 N. [5] [6] It is a colorless, toxic, volatile liquid that is of significant practical interest. [7] Aziridine was discovered in 1888 by the chemist Siegmund Gabriel. [8] Its derivatives, also referred to as aziridines, are of broader interest in medicinal ...
Mitomycin C, an aziridine, is used as a chemotherapeutic agent by virtue of its antitumour activity. [1]In organic chemistry, aziridines are organic compounds containing the aziridine functional group (chemical structure (R−) 4 C 2 N−R), a three-membered heterocycle with one amine (>NR) and two methylene bridges (>CR 2).
The Blum–Ittah aziridine synthesis, also known as the Blum–Ittah-Shahak aziridine synthesis [1] or simply the Blum aziridine synthesis is a name reaction of organic chemistry, for the generation of aziridines from oxiranes.
The Wenker synthesis is an organic reaction converting a beta amino alcohol to an aziridine with the help of sulfuric acid. It is used industrially for the synthesis of aziridine itself. [1] Wenker synthesis. The original Wenker synthesis of aziridine itself takes place in two steps.
The De Kimpe aziridine synthesis is a name reaction of organic chemistry, for the generation of aziridines by the reaction of α-chloroimines with nucleophiles such as hydride, [1] cyanide, or Grignard reagents. [2] [3]
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The aza-Payne rearrangement may be effected in either the "forward" (epoxide to aziridine) or "reverse" (aziridine to epoxide) direction depending on the conditions employed. Electron-poor aziridines undergo the reverse rearrangement in the presence of hydride base, [ 13 ] while the corresponding epoxy amines undergo the forward rearrangement ...
Aziridine; Ethanimine or its tautomer, vinylamine; N-Methylmethanimine This page was last edited on 27 December 2022, at 20:58 (UTC). Text is available under ...