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  2. A value - Wikipedia

    en.wikipedia.org/wiki/A_value

    The A-value for a methyl group is 1.74 as derived from the chemical equilibrium above. This means it costs 1.74 kcal/mol (7.3 kJ/mol) of energy to have a methyl group in the axial position compared to the equatorial position.

  3. Thermodynamic activity - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_activity

    The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.

  4. Femtochemistry - Wikipedia

    en.wikipedia.org/wiki/Femtochemistry

    Femtochemistry is the area of physical chemistry that studies chemical reactions on extremely short timescales (approximately 10 −15 seconds or one femtosecond, hence the name) in order to study the very act of atoms within molecules (reactants) rearranging themselves to form new molecules (products).

  5. Glossary of chemistry terms - Wikipedia

    en.wikipedia.org/wiki/Glossary_of_chemistry_terms

    Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...

  6. Substitution reaction - Wikipedia

    en.wikipedia.org/wiki/Substitution_reaction

    The two reactions are named according tho their rate law, with S N 1 having a first-order rate law, and S N 2 having a second-order. [2] S N 1 reaction mechanism occurring through two steps. The S N 1 mechanism has two steps. In the first step, the leaving group departs, forming a carbocation (C +). In the second step, the nucleophilic reagent ...

  7. Faraday's laws of electrolysis - Wikipedia

    en.wikipedia.org/wiki/Faraday's_laws_of_electrolysis

    Michael Faraday reported that the mass (m) of a substance deposited or liberated at an electrode is directly proportional to the charge (Q, for which the SI unit is the ampere-second or coulomb). [ 3 ] m ∝ Q m Q = Z {\displaystyle m\propto Q\quad \implies \quad {\frac {m}{Q}}=Z}

  8. Academic term - Wikipedia

    en.wikipedia.org/wiki/Academic_term

    First term begins in the second week of September and continues for 15 weeks, ending in mid-December, excluding one week for mid-term break in late October. Second term begins in the first week of January and continues for 12 weeks, ending at the end of March. Third term begins early/mid-April and continues for 11 weeks until the end of June.

  9. FWC - Wikipedia

    en.wikipedia.org/wiki/FWC

    FWC may refer to: Fairfield Municipal Airport (Illinois), in the United States; Fair Work Commission, in Australia; Far West Capital, an American financial services company; FIFA World Cup, an international football (soccer) competition held every four years