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A substance is pyrophoric (from Ancient Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). [1] Examples are organolithium compounds and triethylborane.
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction.
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula P H 3, classed as a pnictogen hydride.Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P 2 H 4).
For corrosion protection in nuclear reactors of the light water reactor design, depleted zinc oxide is produced by first passing diethylzinc through an enrichment centrifuge. The pyrophoricity of diethylzinc can be used to test the inert atmosphere inside a glovebox. An oxygen concentration of only a few parts per million will cause a bottle of ...
White phosphorus is the first allotrope of phosphorus, and in fact the first elementary substance to be discovered that was not known since ancient times. [3] It glows greenish in the dark (when exposed to oxygen) and is highly flammable and pyrophoric (self-igniting) upon contact with air.
A number of fatal industrial accidents produced by combustion and detonation of leaked silane in air have been reported. [20] [21] [22] Due to weak bonds and hydrogen, silane is a pyrophoric gas (capable of autoignition at temperatures below 54 °C or 129 °F). [23]
tert-butyllithium is a pyrophoric substance, meaning that it spontaneously ignites on exposure to air. Air-free techniques are important so as to prevent this compound from reacting violently with oxygen and moisture: t-BuLi + O 2 → t-BuOOLi t-BuLi + H 2 O → t-BuH + LiOH. The solvents used in common commercial preparations are themselves ...