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A cyclohexane molecule in chair conformation. Hydrogen atoms in axial positions are shown in red, while those in equatorial positions are in blue. Cyclohexane conformations are any of several three-dimensional shapes adopted by molecules of cyclohexane. Because many compounds feature structurally similar six-membered rings, the structure and ...
A value. The A-value for a methyl group is 1.74 as derived from the chemical equilibrium above. This means it costs 1.74 kcal/mol (7.3 kJ/mol) of energy to have a methyl group in the axial position compared to the equatorial position. A-values are numerical values used in the determination of the most stable orientation of atoms in a molecule ...
IUPAC nomenclature of organic chemistry. In chemical nomenclature, the IUPAC nomenclature of organic chemistry is a method of naming organic chemical compounds as recommended [1][2] by the International Union of Pure and Applied Chemistry (IUPAC). It is published in the Nomenclature of Organic Chemistry (informally called the Blue Book). [3]
Cyclohexane is a colourless, flammable liquid with a distinctive detergent-like odor, reminiscent of cleaning products (in which it is sometimes used). Cyclohexane is mainly used for the industrial production of adipic acid and caprolactam, which are precursors to nylon. [5] Cyclohexyl (C 6 H 11) is the alkyl substituent of cyclohexane and is ...
Boiling point. 158 to 160 °C (316 to 320 °F; 431 to 433 K) Solubility in water. Low. Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references. Cyclohexanethiol is a thiol with the formula C 6 H 11 SH. It is a colorless liquid with a strong odor.
Electrophilic aromatic substitution (SEAr) is an organic reaction in which an atom that is attached to an aromatic system (usually hydrogen) is replaced by an electrophile. Some of the most important electrophilic aromatic substitutions are aromatic nitration, aromatic halogenation, aromatic sulfonation, alkylation Friedel–Crafts reaction and ...
The α- and β-anomers of D-glucopyranose.. In organic chemistry, the anomeric effect or Edward-Lemieux effect (after J. T. Edward and Raymond Lemieux) is a stereoelectronic effect that describes the tendency of heteroatomic substituents adjacent to a heteroatom within a cyclohexane ring to prefer the axial orientation instead of the less-hindered equatorial orientation that would be expected ...
Critical point. 554 K (281 °C), 4070 kPa. Std enthalpy change of fusion, Δ fusH o. 2.68 kJ/mol crystal I → liquid. Std entropy change of fusion, Δ fusS o. 9.57 J/ (mol·K) crystal I → liquid. Std enthalpy change of vaporization, Δ vapH o. 32 kJ/mol. Std entropy change of vaporization, Δ vapS o.