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A cyclohexane molecule in chair conformation. Hydrogen atoms in axial positions are shown in red, while those in equatorial positions are in blue. Cyclohexane conformations are any of several three-dimensional shapes adopted by molecules of cyclohexane. Because many compounds feature structurally similar six-membered rings, the structure and ...
trans -but-2-ene. Cis–trans isomerism, also known as geometric isomerism, describes certain arrangements of atoms within molecules. The prefixes " cis " and " trans " are from Latin: "this side of" and "the other side of", respectively. [ 1 ] In the context of chemistry, cis indicates that the functional groups (substituents) are on the same ...
trans-1,2-Diaminocyclohexane is an organic compound with the formula C 6 H 10 (NH 2) 2. This diamine is a building block for C2 -symmetric ligands that are useful in asymmetric catalysis. [1] A mixture of all three stereoisomers of 1,2-diaminocyclohexane is produced by the hydrogenation of o -phenylenediamine.
A Newman projection is a drawing that helps visualize the 3-dimensional structure of a molecule. [1] This projection most commonly sights down a carbon-carbon bond, making it a very useful way to visualize the stereochemistry of alkanes. A Newman projection visualizes the conformation of a chemical bond from front to back, with the front atom ...
Structural isomer. In chemistry, a structural isomer (or constitutional isomer in the IUPAC nomenclature [ 1 ]) of a compound is another compound whose molecule has the same number of atoms of each element, but with logically distinct bonds between them. [ 2 ][ 3 ] The term metamer was formerly used for the same concept. [ 4 ]
Critical point. 554 K (281 °C), 4070 kPa. Std enthalpy change of fusion, Δ fusH o. 2.68 kJ/mol crystal I → liquid. Std entropy change of fusion, Δ fusS o. 9.57 J/ (mol·K) crystal I → liquid. Std enthalpy change of vaporization, Δ vapH o. 32 kJ/mol. Std entropy change of vaporization, Δ vapS o.
Conformational isomerism. Rotation about single bond of butane to interconvert one conformation to another. The gauche conformation on the right is a conformer, while the eclipsed conformation on the left is a transition state between conformers. Above: Newman projection; below: depiction of spatial orientation.
1,2-Diaminocyclohexane (DACH) is an organic compound with the formula (CH 2) 4 (CHNH 2) 2. It is a mixture of three stereoisomers: cis -1,2-diaminocyclohexane and both enantiomers of trans -1,2-diaminocyclohexane. The mixture is a colorless, corrosive liquid, although older samples can appear yellow. It is often called DCH-99 and also DACH.