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This reagent is generated by treating 9-BBN with α-pinene. [2] This sterically crowded chiral trialkylborane can stereoselectively reduce aldehydes in what is known as the Midland Alpine borane reduction, or simply the Midland reduction. [3] C 8 H 12 B-pinanyl + RCDO → C 8 H 12 BOCHDR + (+)-d-pinene. Hydrolysis of the resulting borinic ester ...
9-Borabicyclo[3.3.1]nonane or 9-BBN is an organoborane compound. This colourless solid is used in organic chemistry as a hydroboration reagent. The compound exists as a hydride-bridged dimer, which easily cleaves in the presence of reducible substrates. [1] 9-BBN is also known by its nickname 'banana borane'. [2]
In the same year, M. M. Midland discovered B-3-alpha-pinanyl-9-BBN as the reducing agent, which could be easily available by reacting (+)-alpha-pinene with 9-BBN. The new reducing agent was later commercialized by Aldrich Co. under the name Alpine Borane and the asymmetric reduction of carbonyl groups with either enantiomer of Alpine-Borane is ...
9-硼二环[3.3.1]壬烷 Metadata This file contains additional information, probably added from the digital camera or scanner used to create or digitize it.
B3 (stock exchange), the Bochvar logic in calculus; B03, Alekhine's Defence chess code; B3: Battle by the Bay, a 1996 Street Fighter tournament; B3 oil field, an oil and gas field in the Baltic sea; Model B3 chair, a 1925 German Wassili designer chair; A subclass of B-class stars in stellar classification
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BBN might refer to: Bayesian belief network , a probabilistic graphical model that represents a set of random variables and their conditional independencies via a directed acyclic graph Bible Broadcasting Network , a global Christian radio network headquartered in Charlotte, North Carolina
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