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Diatomic molecules are normally in their lowest or ground state, which conventionally is also known as the state. When a gas of diatomic molecules is bombarded by energetic electrons, some of the molecules may be excited to higher electronic states, as occurs, for example, in the natural aurora; high-altitude nuclear explosions; and rocket ...
For heteronuclear diatomic molecules, the u/g symbol does not correspond to any exact symmetry of the electronic molecular Hamiltonian. In the case of less symmetric molecules the molecular term symbol contains the symbol of the group representation to which the molecular electronic state belongs. It has the general form:
The electrons in diatomic carbon are distributed among the molecular orbitals according to the Aufbau principle to produce unique quantum states, with corresponding energy levels. The state with the lowest energy level, or ground state, is a singlet state (1 Σ + g), which is systematically named ethene-1,2-diylidene or dicarbon(0•). There ...
The LCAO-MO method is used in conjunction to further describe the state of the molecule. [13] Diatomic molecules consist of a bond between only two atoms. They can be broken into two categories: homonuclear and heteronuclear. A homonuclear diatomic molecule is one composed of two atoms of the same element. Examples are H 2, O 2, and N 2. A ...
The lowest excited state of the diatomic oxygen molecule is a singlet state. It is a gas with physical properties differing only subtly from those of the more prevalent triplet ground state of O 2 . In terms of its chemical reactivity, however, singlet oxygen is far more reactive toward organic compounds.
In homonuclear diatomic molecules, the permanent electric dipole moment vanishes and there is no pure rotation spectrum (but see N.B. below). Heteronuclear diatomic molecules possess a permanent electric dipole moment and exhibit spectra corresponding to rotational transitions, without change in the vibronic state.
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Their use is standard practice for the designation of electronic states of diatomic molecules, whereas for atomic states the terms even and odd are used. The ground state (the lowest state) of + is denoted X 2 Σ + g [13] or 1sσ g and it is gerade. There is also the first excited state A 2 Σ + u (2pσ u), which is ungerade.