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In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section crystal systems below). [ 1 ]
Crystals can be classified in three ways: lattice systems, crystal systems and crystal families. The various classifications are often confused: in particular the trigonal crystal system is often confused with the rhombohedral lattice system, and the term "crystal system" is sometimes used to mean "lattice system" or "crystal family".
The crystal system of rhodochrosite is trigonal, with a structure and cleavage in the carbonate rhombohedral system. The carbonate ions ( CO 2− 3 ) are arranged in a triangular planar configuration, and the manganese ions (Mn 2+ ) are surrounded by six oxygen ions in an octahedral arrangement.
Well known crystalline forms are α-rhombohedral (α-R), β-rhombohedral (β-R), and β-tetragonal (β-T). In special circumstances, boron can also be synthesized in the form of its α-tetragonal (α-T) and γ-orthorhombic (γ) allotropes. Two amorphous forms, one a finely divided powder and the other a glassy solid, are also known.
This category lists every crystal element that exists in a rhombohedral structure at STP. Pages in category "Chemical elements with rhombohedral structure" The following 6 pages are in this category, out of 6 total.
Absolute configuration is typically relevant in organic molecules where carbon is bonded to four different substituents. This type of construction creates two possible enantiomers . Absolute configuration uses a set of rules to describe the relative positions of each bond around the chiral center atom.
In organic chemistry, planar, three-connected carbon centers that are trigonal planar are often described as having sp 2 hybridization. [2] [3] Nitrogen inversion is the distortion of pyramidal amines through a transition state that is trigonal planar. Pyramidalization is a distortion of this molecular shape towards a tetrahedral molecular ...
Graphite consists of sheets of trigonal planar carbon. [18] [19] The individual layers are called graphene. In each layer, each carbon atom is bonded to three other atoms forming a continuous layer of sp 2 bonded carbon hexagons, like a honeycomb lattice with a bond length of 0.142 nm, and the distance between planes is 0.335 nm. [20]