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The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: Temperature 298.15 K (25.00 °C; 77.00 °F); Effective concentration (activity) 1 mol/L for each aqueous or amalgamated (mercury-alloyed) species; Unit activity for each solvent and pure solid or liquid species; and
Metallic hydrogen (recombination energy) 216 [2] Specific orbital energy of Low Earth orbit (approximate) 33.0: Beryllium + Oxygen: 23.9 [3] Lithium + Fluorine: 23.75 [citation needed] Octaazacubane potential explosive: 22.9 [4] Hydrogen + Oxygen: 13.4 [5] Gasoline + Oxygen –> Derived from Gasoline: 13.3 [citation needed] Dinitroacetylene ...
The formal potential is thus the reversible potential of an electrode at equilibrium immersed in a solution where reactants and products are at unit concentration. [4] If any small incremental change of potential causes a change in the direction of the reaction, i.e. from reduction to oxidation or vice versa , the system is close to equilibrium ...
Bipolar electrochemistry scheme. In electrochemistry, standard electrode potential, or , is a measure of the reducing power of any element or compound.The IUPAC "Gold Book" defines it as; "the value of the standard emf (electromotive force) of a cell in which molecular hydrogen under standard pressure is oxidized to solvated protons at the left-hand electrode".
Most electrodes work over a limited range of conditions, such as pH or temperature, outside of this range the electrodes behavior becomes unpredictable. The advantage of a pseudo-reference electrode is that the resulting variation is factored into the system allowing researchers to accurately study systems over a wide range of conditions.
The electrode potential may be either that at equilibrium at the working electrode ("reversible potential"), or a potential with a non-zero net reaction on the working electrode but zero net current ("corrosion potential", "mixed potential"), or a potential with a non-zero net current on the working electrode (like in galvanic corrosion or ...
What replaced it was a theoretical electrode/solution interface, where the concentration of H + was 1 M, but the H + ions were assumed to have no interaction with other ions (a condition not physically attainable at those concentrations). To differentiate this new standard from the previous one, it was given the name 'standard hydrogen electrode'.
V is the unit volt M denotes the electrode made of metal M (abs) denotes the absolute potential (SHE) denotes the electrode potential relative to the standard hydrogen electrode. A different definition for the absolute electrode potential (also known as absolute half-cell potential and single electrode potential) has also been discussed in the ...