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The chirality of a molecule that has a helical, propeller, or screw-shaped geometry is called helicity [5] or helical chirality. [6] [7] The screw axis or the D n, or C n principle symmetry axis is considered to be the axis of chirality. Some sources consider helical chirality to be a type of axial chirality, [7] and some do not.
Macroscopic examples of chirality are found in the plant kingdom, the animal kingdom and all other groups of organisms. A simple example is the coiling direction of any climber plant, which can grow to form either a left- or right-handed helix. In anatomy, chirality is found in the imperfect mirror image symmetry of many kinds of animal bodies.
Helicity is a pseudo-scalar quantity: it changes sign under change from a right-handed to a left-handed frame of reference; it can be considered as a measure of the handedness (or chirality) of the flow. Helicity is one of the four known integral invariants of the Euler equations; the other three are energy, momentum and angular momentum.
[7] If two enantiomers easily interconvert, the pure enantiomers may be practically impossible to separate, and only the racemic mixture is observable. This is the case, for example, of most amines with three different substituents (NRR′R″), because of the low energy barrier for nitrogen inversion.
Since the helicity of massive particles is frame-dependent, it might seem that the same particle would interact with the weak force according to one frame of reference, but not another. The resolution to this paradox is that the chirality operator is equivalent to helicity for massless fields only, for which helicity is not frame-dependent. By ...
Pamela Anderson was asked during an interview on the “Happy Sad Confused” podcast if she’s ever been mistaken for another celebrity, and her answer ended up being quite shocking.
In organic chemistry, helicenes are ortho-condensed polycyclic aromatic compounds in which benzene rings or other aromatics are angularly annulated to give helically-shaped chiral molecules. [1] The chemistry of helicenes has attracted continuing attention because of their unique structural, spectral , and optical features.
U.S. Surgeon General Vivek H. Murthy shared a very fruitful tutorial on cutting a mango — along with some juicy stories.
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