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The chirality of a molecule that has a helical, propeller, or screw-shaped geometry is called helicity [5] or helical chirality. [6] [7] The screw axis or the D n, or C n principle symmetry axis is considered to be the axis of chirality. Some sources consider helical chirality to be a type of axial chirality, [7] and some do not.
The systematic naming for this class of compounds is based on the number of rings: [n]helicene is the structure consisting of n rings. According to IUPAC, only structures where n is at least 5 are considered helicenes. [1] Some specific compounds also have alternate or trivial names.
To see an in depth discussion of the two with examples, which also shows how chirality and helicity approach the same thing as speed approaches that of light, click the link entitled "Chirality and Helicity in Depth" on the same page. History of science: parity violation; Helicity, Chirality, Mass, and the Higgs (Quantum Diaries blog)
Helicity is a pseudo-scalar quantity: it changes sign under change from a right-handed to a left-handed frame of reference; it can be considered as a measure of the handedness (or chirality) of the flow. Helicity is one of the four known integral invariants of the Euler equations; the other three are energy, momentum and angular momentum.
It is also rotationally invariant, in that a rotation applied to the system leaves the helicity unchanged. Helicity, however, is not Lorentz invariant; under the action of a Lorentz boost, the helicity may change sign. Consider, for example, a baseball, pitched as a gyroball, so that its spin axis is aligned with the direction of the pitch. It ...
Macroscopic examples of chirality are found in the plant kingdom, the animal kingdom and all other groups of organisms. A simple example is the coiling direction of any climber plant, which can grow to form either a left- or right-handed helix. In anatomy, chirality is found in the imperfect mirror image symmetry of many kinds of animal bodies.
The two-component helicity eigenstates satisfy ^ (^) = (^) where are the Pauli matrices, ^ is the direction of the fermion momentum, = depending on whether spin is pointing in the same direction as ^ or opposite.
An example of a molecule that does not have a mirror plane or an inversion and yet would be considered achiral is 1,1-difluoro-2,2-dichlorocyclohexane (or 1,1-difluoro-3,3-dichlorocyclohexane). This may exist in many conformers ( conformational isomers ), but none of them has a mirror plane.