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A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds or through the sharing of electrons as in covalent bonds, or some combination of these effects.
A crystal's crystallographic forms are sets of possible faces of the crystal that are related by one of the symmetries of the crystal. For example, crystals of galena often take the shape of cubes, and the six faces of the cube belong to a crystallographic form that displays one of the symmetries of the isometric crystal system. Galena also ...
A crystal system is a set of point groups in which the point groups themselves and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one lattice system, in which case the crystal system and lattice system both have the same name.
Most ionic compounds exist in the form of a crystal structure, in which the ions occupy the corners of the crystal. Such a structure is called a crystal lattice. Ionic compounds lose their crystal lattice structure and break up into ions when dissolved in water or any other polar solvent. This process is called solvation.
One form of an element may be a molecular solid, but another form of that same element may not be a molecular solid. [3] [4] [5] For example, solid phosphorus can crystallize as different allotropes called "white", "red", and "black" phosphorus. White phosphorus forms molecular crystals composed of tetrahedral P 4 molecules. [32]
Solid-phase electrical conductivity: Variable, [6] depending on the nature of the bonding: network solids in which all electrons are used for sigma bonds (e.g. diamond, quartz) are poor conductors, as there are no delocalized electrons. However, network solids with delocalized pi bonds (e.g. graphite) or dopants can exhibit metal-like conductivity.
In chemistry, an ionic crystal is a crystalline form of an ionic compound. They are solids consisting of ions bound together by their electrostatic attraction into a regular lattice . Examples of such crystals are the alkali halides , including potassium fluoride (KF), potassium chloride (KCl), potassium bromide (KBr), potassium iodide (KI ...
In the crystal (CsF has the NaCl structure with both ions being 6-coordinate) if each bond has 9% covalent character the total covalency of Cs and F would be 54%. This would be represented by one bond of around 50% covalent character resonating between the six positions and the overall effect would be to reduce the charge on Cs to about + 0.5 ...