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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
The dividing line between metals and nonmetals can be found, in varying configurations, on some representations of the periodic table of the elements (see mini-example, right). Elements to the lower left of the line generally display increasing metallic behaviour; elements to the upper right display increasing nonmetallic behaviour.
Periodic table of the chemical elements showing the most or more commonly named sets of elements (in periodic tables), and a traditional dividing line between metals and nonmetals. The f-block actually fits between groups 2 and 3 ; it is usually shown at the foot of the table to save horizontal space.
Here [Ne] refers to the core electrons which are the same as for the element neon (Ne), the last noble gas before phosphorus in the periodic table. The valence electrons (here 3s 2 3p 3) are written explicitly for all atoms.
Dmitri Mendeleev, Russian chemist who proposed the periodic table: f-block groups 7 f-block [258] (10.3) (1100) – – 1.3 – synthetic unknown phase 102 No Nobelium: Alfred Nobel, Swedish chemist and engineer f-block groups 7 f-block [259] (9.9) (1100) – – 1.3 – synthetic unknown phase 103 Lr Lawrencium: Ernest Lawrence, American ...
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• the turquoise nickel cation Ni 2+ from NiCl 2 • the blue copper cation Cu 2+ from CuSO 4 • the purple manganese oxyanion MnO − 4 from KMnO 4 . This table lists the ionic species that are most likely to be present, depending on pH, in aqueous solutions of binary salts of metal ions.
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